Entanglement lies at the heart of quantum mechanics and challenged the intuition of physicists ever since it was discovered. At the same time, it is a powerful tool that serves as a key resource for quantum communication and quantum computation schemes. Many of these applications rely on multiparticle entanglement, whose description, generation and manipulation became therefore a very active field in theoretical and experimental quantum information science. The goals are here to classify and understand the different types of entanglement, to find new applications and to control and analyze the quantum states experimentally.\n\nIn this thesis, the experimental observation and analysis of two different types of four-photon polarization entangled states is presented: The cluster state and the symmetric Dicke state with two excitations. For this purpose, experimental setups based on spontaneous parametric down conversion and linear optics with conditional detection were designed. They allowed to observe the cluster state with a fidelity of 74.1 % and the symmetric Dicke state with a fidelity of 84.4 %. The cluster state experiment included the development of a new instrument that is of interest for linear optics quantum logic in general: A probabilistic controlled phase gate that is, due to the simplification of a previous approach, highly stable and can actually be used in multiphoton experiments. The quality of the gate is evaluated by analyzing its entangling capability and by performing full process tomography. The achieved results demonstrate that this device is well suited for implementation in various multiphoton quantum information protocols.\n\nIn order to study the observed quantum states, efficient analysis tools are introduced. It was possible to verify that essential properties of the ideal states are indeed reproduced in the experiment, among others, the presence of genuine four-partite entanglement. A particular focus is put on the behavior of the states under projective measurements and photon loss. Several new insights in their entanglement structure are revealed and verified experimentally. We further demonstrate properties that are characteristic for the entanglement classes of the states. These can be used to infer the applicability of the observed states for certain distributed quantum communication applications.\n\nThe presented experiments are generic for the design of setups to observe cluster- and symmetric Dicke states with a higher number of photons. Furthermore, also the efficient non-tomographic methods for state analysis we employ can directly be generalized to experiments with higher qubit numbers, where the reduction of the experimental effort for state analysis is even more crucial.